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العنوان
Investigation an innovative technology for biofuels production /
المؤلف
Radwan, Mayada Mamdouh Salah.
هيئة الاعداد
باحث / مياده ممدوح صلاح رضوان
مشرف / زكريا ابراهيم اسماعيل
مشرف / علي ابراهيم موسي
مشرف / طارق حسني الشبراوي
الموضوع
Biofuels production.
تاريخ النشر
2022.
عدد الصفحات
188 p. :
اللغة
الإنجليزية
الدرجة
الدكتوراه
التخصص
الزراعية والعلوم البيولوجية (المتنوعة)
تاريخ الإجازة
1/1/2022
مكان الإجازة
جامعة المنصورة - كلية الزراعة - قسم الهندسة الزراعية
الفهرس
Only 14 pages are availabe for public view

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from 187

Abstract

Energy consumption is escalating day by day because of the rising population ‎and rapid economic growth rate. ‎Extensive use of petroleum-based fuels results in emissions of highly complex ‎mixtures, which cause a potential impact on human health and environmental pollution ‎to global warming and a decrease in energy reserve. Biodiesel has been one of the main ‎alternative energy resources to substitute petroleum-based fuel, owing to its attractive ‎properties such as emissions reduction, sustainability, and renewability. So, this study ‎aims to investigate an innovative technology for biodiesel production, High ‎Voltage Technic combined with electrical heating (HVTEH), and purify the product of ‎biodiesel using dry wash‏ ‏systems. And evaluate the properties of produced biodiesel ‎by testing it on the engine under different ratios of 60%, 70% and 80% by adding ‎5% ‎gasoline and 3% turpentine oil.‎The experiments were carried out with the cooperation between the Department ‎of Agriculture Engineering, Faculty of Agricultural, Mansoura University and the ‎Tractor Test Station Department of Forces and Energy, Sabahia, Alexandria. The ‎experiments are conducted from April 2021until August 2022, with the cooperation ‎between the Department of Agriculture Engineering, Faculty of Agricultural, ‎Mansoura University and Mechanical Engineering Department, Engineering Research ‎Division, National Research Centre, Dokki, Giza, Egypt.‎The main steps to fulfill the requirements of this aim including:-‎Description of the developed Biodiesel device ‎‎1-Unit for mixing chemical materials ‎2-Unit for filtration oil ‎3-Unit for glycerin separation by High Voltage Technic combined with electrical ‎heating (HVTEH)‎ ‎5- Electric heater ‎6-High voltage unit to separating biodiesel ‎7-Electric motor Biodiesel was produced from used cooking oil (UCO) by a transesterification ‎system. The UCO heating at 60 °C and mixing it with methanol in a volume ratio of ‎‎(methyl alcohol to oil) 1: 5 presence of a catalyst (potassium hydroxide). Then ‎use‎‎ innovative technology of High Voltage Technic combined with electrical heating ‎‎(HVTEH) is investigated. The impurities in the biodiesel (methanol-water content - ‎glycerol - soap content) were measured before and after the biodiesel purification ‎process.‎ The purification was conducted under three dry washing materials firstly; is date palm ‎fiber, secondly; is burlap and finally; is felt. The results were compared by sing the ‎American standard specifications. The efficiency of the different purification materials ‎under regulated the discharge and pressure of the purification filter was identified. ‎Also, measuring the physical properties of petroleum diesel (B0), biodiesel 100% ‎‎(B100), and biodiesel blended with diesel of 60% (B60), 70% (B70), and 80% (B80) ‎and the biodiesel blend effect on the engine performance and emission profile. ‎The results during determining the amount of glycerol separating from biodiesel ‎using new technology High Voltage Technic combined with electrical heating ‎‎(HVTEH) revealed that: ‎‎1-‎The glycerol separation time increased by increasing distance between electrode ‎and quantity of sample. On the other hand, the maximum amount of glycerol’s ‎separation was 650 and 4600 mL for 5.0 and 35.0L of sample quantity, ‎respectively at a separation voltage of 5.0 k. This amount of glycerol achieved ‎about 13.0% as a percentage relative to the amount of sample.‎‎2-‎Increasing the distance between electrodes by about 2.0 times (from 25to ‎‎50mm), the amount of glycerol separated per unit time decreased by around ‎‎39.98% (from 2.166 mL/s at25mm to 1.3mL/s at 50mm distance between ‎electrodes). This relation decreased to 57.52% (from 2.166mL/s to 0.92mL/s) by ‎increasing the distance between the electrodes by 3.0 times from the first one.‎‎3- ‎The rate of glycerol separating proportional increases by increasing the ‎separating voltage from 5.0 kV to 10 kV, from 10 kV to 20 kV, and from 20 kV ‎to 30 kV, respectively. Consequently, the requirement of separating time ‎decreases. At the span 25mm between the electrode, the AQSG decreased by ‎about 60% and 33% by increasing the separating voltage two times (from 5kVto ‎‎30 kV) at 5.0 and 35.0 L, espectively.‎‎4-‎The amounts of glycerol separation (AQG mL) decreased by about 24% and ‎‎23% for the separating simple of 5.0 and 35.0 L, respectively under 50 mm ‎distance between electrodes. Whereas, the AQG decreased by about 17.14% ‎and 17.65% by increasing the separating voltage from 5.0 kV to 30 kV under ‎‎75mm distance between electrodes.‎‎5-‎The use of the copper electrode proved its effectiveness in accelerating the ‎glycerol separation time after graphite and iron. But graphite outperformed them ‎because it does not form chemical oxides on the electrode, which in turn reduces ‎the efficiency of any metal electrode.‎‎6-‎The study showed that the purification of ‎biodiesel with Date palm fiber (dry ‎washing) is more efficient in removing both methanol (94.56%) ‎and water ‎content (94.9%) and soap content (91.14%) than other purification materials ‎‎(Burlap and Felt), while all of the purified materials in case of glycerol have ‎similar efficiency‎.‎‎7-‎The quantity of impurities decreased when using low discharge (2.38 L/min) and ‎low pressure (0.2 bar), as well as the second filter, is more effective than using ‎one filter.‎‎8-‎The chemical and physical properties of biodiesel blended in percentages of ‎volume (60%, 70%, and 80%) with petroleum diesel have nearly similar values ‎with petroleum diesel in the case of density and Cetane number. While the ‎values of the biodiesel mixture in the case of calorific value and viscosity had ‎higher values than petroleum diesel and the values of the biodiesel mixture in the ‎case of flash point had lower values than petroleum diesel. ‎9- ‎Specific fuel consumption for B80 increased by about 4.8% compared to diesel ‎fuel but for B60 increased by about 3.85%. Thermal efficiency for B60 and B80 ‎decreased by up to 12.9% compared to diesel fuel, but at B70 recorded 9.7%. ‎Exhaust gas temperature decreased at using B80 by about 1.84% compared to ‎diesel fuel. While using B60 and B70 exhaust gas temperature increased by up ‎to 3.29% and 2.47%, respectively. Volumetric efficiency decreased for B60, ‎B70, and B80 at the same ratio of about 2%. The air-fuel ratio of B60, B70, and ‎B80 decreased to about 5.3%. The above results depict that B80 gives better ‎engine performance.‎‎10-‎Comparison of diesel engine exhaust emissions fuelled with B60 and B70, and ‎B80 at 100% of engine load compared with the results for diesel fuel. CO2 ‎emission for B70 decreased by up to 2.67% compared to diesel fuel. But for ‎B80, the CO2 emission decreased to 0.63%, and for B60, it increased to 16%. ‎The CO emission decreased for B70 by about 12.67% and for B80 by up to ‎‎11.33% and for B60 by up to 6%. The NOx emission for B60 decreased to ‎‎5.41% in comparison with diesel fuel but for B80 by up to 2.77% and for B70 ‎by up to 1.58%. The HC emission decreased for B80 by about 20% and for B70 ‎by up to 16% but for B60, it was increased by up to 4%. The smoke emission for ‎B80 decreased up to 37.5% compared to diesel fuel and decreased for B70 by ‎up to 37.3% but for B60 it is increased to 49.6%. It is seen that the overall ‎engine emissions were better for B80.‎‎5.2 CONCLUSSION‎ ‎1-‎The results indicated that using a new technology High Voltage Technic ‎combined with electrical heating (HVTEH) affecting the time required for separation ‎process. Also, distance between electrode and voltage are a significant factors reducing ‎the separation glycerol time, using this technic compared to gravity method due ‎separation process in a period less than a minutes. ‎‎2-‎Results of using various distance between electrodes (25, 50 and 75mm) under ‎different voltage (5.0, 10.0, 20 and 30 kV) proved that distance between ‎electrode 25mm and high voltage (30kV) intensity has most effective reducing ‎the glycerin separation time.‎‎3-‎The method of biodiesel purification using date palm fiber (dry washing) is more ‎efficient during sanitization methanol and water content and soap content than ‎the other two purification materials. In the meantime, all the purification ‎methods have similar efficiency in getting rid of glycerol. ‎‎4-‎The chemical and physical properties of biodiesel blended in percentages of ‎volume (60%, 70%, and 80%) with petroleum diesel have nearly similar values ‎with petroleum diesel in the case of density and Cetane number. But the ‎calorific values and viscosity of the biodiesel mixture had higher values than ‎petroleum diesel. The biodiesel mixture values in the case of flash point had ‎lower values than petroleum diesel. ‎‎5-‎The blended ratio of B80 with petroleum diesel led to a limited reduction for ‎each of; the emissions of carbon monoxide, carbon dioxide gases, the exhaust ‎gas temperature, HC & smoke, and NOx. But, the specific fuel consumption ‎increased at all the different ratios.‎